A student performed the following procedures to study various photosynthetic pigments (light-absorbing chemicals) in tree leaves and the wavelengths of light they absorb.

Experiment 1:

The student obtained samples of leaves from oaks, maples, ashes, sycamores, and poplars. Each leaf sample was ground separately with a mortar and pestle to release the pigments, and then each sample was suspended in water to make a colored solution of the pigment. The student then measured the absorption spectrum (a graph of how much light is absorbed by a pigment at varying wavelengths of light) of each solution in a device called a spectrophotometer. The setup of a spectrophotometer is shown below in Diagram 1.

The light source emits white light, which is split into its various wavelengths by the prism. Next, a slit, which can be moved up or down to select a particular wavelength, is used to transmit just a single wavelength to the sample. The sample absorbs a fraction of this light that is characteristic to the pigment in the sample, and the rest is transmitted to the detector for a readout. Using the spectrophotometer, the student found the λmax (the wavelength of light in nanometers (nm) that the pigment absorbs most intensely, for each sample) and recorded the results in Table 1. Table 1 also shows the transmittance and absorbance values at λmax. Transmittance, T, is defined as the fraction of light, expressed as a decimal, which passes through the sample. Absorbance, A, is given by:

A = –log(T) or 10–A = T

Experiment 2:

A student is given a leaf from an unknown source. She crushes and extracts the pigment according to the procedure in Experiment 1. Measuring the absorbance spectrum in the spectrophotometer produces the following readout, shown in Diagram 2.

Diagram 2

A standardized sample of a pigment often found in plant leaves, called Chlorophyll A, was placed into the spectrophotometer and found to have a λmaxof 425 nm. The leaves of which tree most likely have a high concentration of Chlorophyll A?

A student performed the following procedures to study various photosynthetic pigments (light-absorbing chemicals) in tree leaves and the wavelengths of light they absorb.

Experiment 1:

The student obtained samples of leaves from oaks, maples, ashes, sycamores, and poplars. Each leaf sample was ground separately with a mortar and pestle to release the pigments, and then each sample was suspended in water to make a colored solution of the pigment. The student then measured the absorption spectrum (a graph of how much light is absorbed by a pigment at varying wavelengths of light) of each solution in a device called a spectrophotometer. The setup of a spectrophotometer is shown below in Diagram 1.

The light source emits white light, which is split into its various wavelengths by the prism. Next, a slit, which can be moved up or down to select a particular wavelength, is used to transmit just a single wavelength to the sample. The sample absorbs a fraction of this light that is characteristic to the pigment in the sample, and the rest is transmitted to the detector for a readout. Using the spectrophotometer, the student found the λmax (the wavelength of light in nanometers (nm) that the pigment absorbs most intensely, for each sample) and recorded the results in Table 1. Table 1 also shows the transmittance and absorbance values at λmax. Transmittance, T, is defined as the fraction of light, expressed as a decimal, which passes through the sample. Absorbance, A, is given by:

A = –log(T) or 10–A = T

Experiment 2:

A student is given a leaf from an unknown source. She crushes and extracts the pigment according to the procedure in Experiment 1. Measuring the absorbance spectrum in the spectrophotometer produces the following readout, shown in Diagram 2.

Diagram 2

In Experiment 2, at which of the following wavelengths, in nanometers, is the most amount of light transmitted through the sample?

Chemists can model how solids, liquids, and gases behave at different temperatures and pressures with a graph called a phase diagram. When the pressure and temperature are simultaneously known, a scientist can predict whether the material will be in a specific state. The diagram is divided into sections depending on the phase and the lines between sections represent phase transitions occurring between two or more separate phases.

In general, solids of neatly stacked molecules exist when temperatures are low and pressures are intermediate. These values decrease the kinetic energy of the molecules enough to allow for attractive forces to begin the stacking process. Liquids, by contrast, are found at intermediate pressures and temperatures. The temperature is high enough to impart enough kinetic energy to prevent solid formation and the pressure is high enough to prevent the liquid from becoming a gas. Finally, a gas forms at low pressures and high temperatures. The high level of kinetic energy prevents molecules from associating with one another.

Materials can undergo processes called phase transitions, meaning they can transition from one phase to another. The transition from a solid to a liquid is called melting, while the reverse transition is called freezing. Vaporization occurs when a liquid becomes a gas, while condensation occurs when a gas becomes a liquid. Finally, in a process called sublimation, a solid can directly become a gas without passing through a liquid phase. Additionally, when a gas directly becomes a solid, this is known as deposition.

What property most likely allows for molecules to stack neatly when freezing?

A brilliant but underpaid high school chemistry teacher, together with his former student, manufactures a chemical compound, which they sell for a large mark-up. Their set of reactions are given below:

(1) A + B + C + acid --> D

(2) D --> intermediate

(3) Intermediate --> E

(4) E + acid --> X

His student notes the following observations:

Observation 1) If a greater amount of B and C are used in the reaction, this yields no increased amount of product D.

Observation 2) At any given point, D, the intermediate, and E may co-exist in equal proportions. However, at higher temperatures, higher proportions of product E are noted.

Observation 3) The addition of a strong base can reverse reaction 4.

Without the addition of acid, reactions 1 and 4 proceed at a much slower rate. What is the role of acid in these reactions?

The Millikin oil drop experiment is among the most important experiments in the history of science. It was used to determine one of the fundamental constants of the universe, the charge on the electron. For his work, Robert Millikin won the Nobel Prize in Physics in 1923.

Millikin used an experimental setup as follows in Figure 1. He opened a chamber of oil into an adjacent uniform electric field. The oil droplets sank into the electric field once the trap door opened, but were then immediately suspended by the forces of electricity present in the field.

Figure 1:

By determining how much force was needed to exactly counteract the gravity pulling the oil droplet down, Millikin was able to determine the force of electricity. This is depicted in Figure 2.

Using this information, he was able to calculate the exact charge on an electron. By changing some conditions, such as creating a vacuum in the apparatus, the experiment can be modified.

Figure 2:

When the drop is suspended perfectly, the total forces up equal the total forces down. Because Millikin knew the electric field in the apparatus, the force of air resistance, the mass of the drop, and the acceleration due to gravity, he was able to solve the following equation:

Table 1 summarizes the electric charge found on oil drops in suspension. Millikin correctly concluded that the calculated charges must all be multiples of the fundamental charge of the electron. A hypothetical oil drop contains some net charge due to lost electrons, and this net charge cannot be smaller than the charge on a single electron.

Table 1:

The decision to use oil drops in Millikin's experiment was made after water drops were found to evaporate too quickly.

Another scientist conducts an experiment and places two beakers into sealed chambers within a single larger, constant pressure chamber, as in the figure below. The pressure and temperature conditions in the chambers are all very similar to the conditions used in the Millikin experiment from the passage, without a vacuum.

One beaker contains oil, and one beaker contains water. The volumes of both beakers are identical. Based on the information in the original passage, which of the following is most likely true:

Chemists can model how solids, liquids, and gases behave at different temperatures and pressures with a graph called a phase diagram. When the pressure and temperature are simultaneously known, a scientist can predict whether the material will be in a specific state. The diagram is divided into sections depending on the phase and the lines between sections represent phase transitions occurring between two or more separate phases.

In general, solids of neatly stacked molecules exist when temperatures are low and pressures are intermediate. These values decrease the kinetic energy of the molecules enough to allow for attractive forces to begin the stacking process. Liquids, by contrast, are found at intermediate pressures and temperatures. The temperature is high enough to impart enough kinetic energy to prevent solid formation and the pressure is high enough to prevent the liquid from becoming a gas. Finally, a gas forms at low pressures and high temperatures. The high level of kinetic energy prevents molecules from associating with one another.

Materials can undergo processes called phase transitions, meaning they can transition from one phase to another. The transition from a solid to a liquid is called melting, while the reverse transition is called freezing. Vaporization occurs when a liquid becomes a gas, while condensation occurs when a gas becomes a liquid. Finally, in a process called sublimation, a solid can directly become a gas without passing through a liquid phase. Additionally, when a gas directly becomes a solid, this is known as deposition.

At Point D, the material is most likley in what phase(s)?

Both gases and liquids are considered to be fluids that have individual molecules that move around with kinetic and potential energy. Kinetic energy, defined as the energy related to motion, takes three forms: translational energy that occurs as a molecule moves from position A to position B, rotational energy that occurs as a molecule spins around an imaginary axis at its center of mass, and vibrational energy that occurs as individual atoms in a molecular bond move towards and away from each other. Usually, molecules possess varying combinations of kinetic energy forms. In contrast, potential energy is defined as stored energy that could be released to become kinetic energy. The total energy of a molecule is fixed, meaning that a molecule has some combination of kinetic and potential energies.

Varying amount of kinetic and potential energies define how molecules in a fluid interact with each other. For example, when the kinetic energy of a molecule is high (greater than 1000J), it can no longer interact with neighboring molecules strongly enough to remain a liquid. However, if the potential energies are too high (greater than 1000 J), molecules cannot escape a liquid to become a gas. If the kinetic energy is high and the potential energy is low, molecules tend to become a gas and can be modeled by an equation known as the Ideal Gas Law:

Where P is the pressure of a gas, V is the volume, n is the number of moles of a gas, R is a constant, and T is temperature in degrees Kelvin.

The Ideal Gas Law perfectly applies to particles with no mass, no intermolecular interactions, and no true volume. However, real molecules do not adhere perfectly to the Ideal Gas Law.

At a constant volume, the relationship between pressure and temperature as presented in the passage may best be depicted as:

The Ideal Gas Law is as follows:

is pressure as measured in Pascals, is volume as measured in cubic meters, is the number of moles of the gas, is the gas constant known as 8.314 Joules per mole times Kelvin, and is the temperature measured in Kelvin.

A class of students began studying the Ideal Gas Law and how the Pressure and the Volume relate to one another. They took 20 moles of a sample gas and kept the room at a temperature of 300 Kelvin. They then used different sized containers of the gas to limit and expand the volume. At each different volume, they measure the pressure of the gas on its container. The table they made from their results is seen in table 1.

TABLE 1

FIGURE 1

The graph the students made based on the data is seen in Figure 1.

Pressure is created by the movement of the gas molecules pushing against a container. 0 Kelvin is known as absolute 0, the temperature at which all molecule movement theoretically stops.

What would the pressure be if the temperature of the gas was increased to 273 Kelvin?

The rate of a reversible chemical reaction depends on many factors, including concentrations of the reactants and products, temperature, and presence of enzymes called catalysts. In the forward reaction, two reactants combine to form one product. However, in a reverse reaction, the product is broken down into the two reactants.

In order for a forward reaction to occur, the reactants moving around in the test tube must physically interact with each other. The more often reactants interact with each other, the more produce is formed in the same amount of time. The speed at which reactants combine into products (the rate of the reaction) can be calculated by dividing the amount of a chemical produced in a reaction (often measured in moles) by the time it takes to produce that amount.

In order to determine the effects of reactant and product concentration, temperature, and presence of catalysts on the rate of a reaction, a scientist studied the following reaction:

The scientist varied the conditions of the experiment and measured the rate of the reaction. The results are outlined in Table 1. The units of concentration are moles per liter.

In order to display the relationship between the number of moles of H+ and the rate of the reaction in Experiments 1 and 4, the scientist could:

Chemists can model how solids, liquids, and gases behave at different temperatures and pressures with a graph called a phase diagram. When the pressure and temperature are simultaneously known, a scientist can predict whether the material will be in a specific state. The diagram is divided into sections depending on the phase and the lines between sections represent phase transitions occurring between two or more separate phases.

In general, solids of neatly stacked molecules exist when temperatures are low and pressures are intermediate. These values decrease the kinetic energy of the molecules enough to allow for attractive forces to begin the stacking process. Liquids, by contrast, are found at intermediate pressures and temperatures. The temperature is high enough to impart enough kinetic energy to prevent solid formation and the pressure is high enough to prevent the liquid from becoming a gas. Finally, a gas forms at low pressures and high temperatures. The high level of kinetic energy prevents molecules from associating with one another.

Materials can undergo processes called phase transitions, meaning they can transition from one phase to another. The transition from a solid to a liquid is called melting, while the reverse transition is called freezing. Vaporization occurs when a liquid becomes a gas, while condensation occurs when a gas becomes a liquid. Finally, in a process called sublimation, a solid can directly become a gas without passing through a liquid phase. Additionally, when a gas directly becomes a solid, this is known as deposition.

At Point D, the material is most likley in what phase(s)?